Sorption-enhanced reaction processes /
| Main Author: | |
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| Corporate Author: | |
| Format: | eBook |
| Language: | English |
| Published: |
London :
World Scientific Publishing Europe Ltd.,
[2018]
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| Series: | Sustainable chemistry series ;
volume 1. |
| Subjects: | |
| Online Access: | Connect to the full text of this electronic book |
Table of Contents:
- Preface; About the Authors; 1. Introduction; 1.1. Process Intensification; 1.1.1. History; 1.1.2. Classification; 1.2. Integration of Reaction and Separation Operations; 1.2.1. Multifunctionality; 1.2.2. Potential advantages and disadvantages; 1.2.3. Examples; 1.3. Sorption Enhanced Reaction Processes; 1.3.1. Reaction; 1.3.2. Adsorption; 1.3.3. Adsorptive reactors; 1.3.4. Simulated moving bed reactor (SMBR); 1.3.5. Membrane reactors (MRs); 1.3.6. Applications; 1.4. Conclusions; References; 2. Gas-phase Adsorptive Reactor for Hydrogen Production Processes; 2.1. Hydrogen Economy.
- 2.1.1. Energy demand2.1.2. Hydrogen as a clean fuel; 2.1.3. Hydrogen as an energy carrier; 2.2. Hydrogen Production; 2.2.1. Feedstock; 2.2.2. Technologies; 2.2.3. Hydrogen separation and purification; 2.2.4. Sorption enhanced hydrogen production processes; 2.3. Material Developments; 2.3.1. Catalysts; 2.3.1.1. Active phases and supports; 2.3.1.2. Reaction mechanism; 2.3.1.3. Reforming kinetics; 2.3.2. High temperature CO2 adsorbents; 2.3.2.1. Candidates; 2.3.2.2. Calcium oxide-based materials; 2.3.2.3. Lithium-based adsorbents; 2.3.2.4. Layered double hydroxides/hydrotalcite-like compounds.
- 2.3.2.5. Other candidates2.3.3. Multifunctional materials; 2.3.4. Pellet modelling; 2.4. Reactor Design; 2.4.1. Experimental studies with fixed bed reactors; 2.4.2. Experimental studies with fluidized bed reactors; 2.4.3. Modelling and simulation; 2.5. Regeneration and Cyclic Operation; 2.5.1. Pressure swing; 2.5.2. Temperature swing; 2.6. Practical Applications; 2.7. Conclusions and Future Perspectives; References; 3. Membrane Reactors for Water-Gas Shift; 3.1. Introduction
- The Concept; 3.2. Thermodynamic Aspects; 3.3. Catalysts; 3.4. Mechanisms and Kinetic Models; 3.5. Membrane Types.
- 3.5.1. Dense metal membranes3.5.2. Microporous membranes; 3.5.3. Others; 3.5.4. Membranes for H2 vs. CO2 removal; 3.5.5. Hydrogen permeation mechanism; 3.6. Reactor Configurations; 3.6.1. Packed bed membrane reactors; 3.6.2. Fluidized-bed membrane reactors; 3.6.3. Micro-membrane reactors; 3.6.4. Sorption enhanced membrane reactors (SEMRs); 3.7. Modelling and Simulation; 3.8. Parametric Study: Effect of Operating Variables; 3.8.1. Effect of temperature; 3.8.2. Effect of sweep gas; 3.8.3. Effect of the H2O/CO molar ratio; 3.8.4. Effect of total pressure; 3.8.5. Effect of other parameters.
- 3.9. Practical Applications and Pilot Scale3.10. Conclusions; References; 4. Liquid Phase Simulated Moving Bed Reactor; 4.1. Simulated Moving Bed Technology: The Concept; 4.2. Combining Reaction and Adsorption: Simulated Moving Bed Reactor; 4.3. Process Development; 4.4. SMBR for the Production of Organic Oxygenated Compounds: Acetals and Esters; 4.4.1. Glycerol ethyl acetal; 4.4.2. Butyl acrylate; 4.5. An Integrated Process; 4.6. Combining Reaction, Adsorption and Membrane Permeation: The PermSMBR; 4.7. Conclusions; References; 5. Conclusions and Perspectives; 5.1. Looking Back.