A modern course in statistical physics /
| Main Author: | |
|---|---|
| Corporate Author: | |
| Format: | eBook |
| Language: | English |
| Published: |
Weinheim, Germany :
Wiley-Vch, Verlag GmbH & Co. KGaA,
[2016]
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| Edition: | 4th revised and updated edition. |
| Subjects: | |
| Online Access: | Connect to the full text of this electronic book |
Table of Contents:
- 2.1. Introduction
- 2.2. Counting Microscopic States
- 2.3. Probability
- 2.4. Multiplicity and Entropy of Macroscopic Physical States
- 2.5. Multiplicity and Entropy of a Spin System
- 2.5.1. Multiplicity of a Spin System
- 2.5.2. Entropy of Spin System
- 2.6. Entropic Tension in a Polymer
- 2.7. Multiplicity and Entropy of an Einstein Solid
- 2.7.1. Multiplicity of an Einstein Solid
- 2.7.2. Entropy of the Einstein Solid
- 2.8. Multiplicity and Entropy of an Ideal Gas
- 2.8.1. Multiplicity of an Ideal Gas
- 2.8.2. Entropy of an Ideal Gas
- 2.9. Problems
- 3.1. Introduction
- 3.2. Energy Conservation
- 3.3. Entropy
- 3.3.1. Carnot Engine
- 3.3.2. The Third Law
- 3.4. Fundamental Equation of Thermodynamics
- 3.5. Thermodynamic Potentials
- 3.5.1. Internal Energy
- 3.5.2. Enthalpy
- 3.5.3. Helmholtz Free Energy
- 3.5.4. Gibbs Free Energy
- 3.5.5. Grand Potential
- 3.6. Response Functions
- 3.6.1. Thermal Response Functions (Heat Capacity)
- 3.6.2. Mechanical Response Functions
- 3.7. Stability of the Equilibrium State
- 3.7.1. Conditions for Local Equilibrium in a PVT System
- 3.7.2. Conditions for Local Stability in a PVT System
- 3.7.3. Implications of the Stability Requirements for the Free Energies
- 3.7.4. Correlations Between Fluctuations
- 3.8. Cooling and Liquefaction of Gases
- 3.9. Osmotic Pressure in Dilute Solutions
- 3.10. The Thermodynamics of Chemical Reactions
- 3.10.1. The Affinity
- 3.11. The Thermodynamics of Electrolytes
- 3.11.1. Batteries and the Nernst Equation
- 3.11.2. Cell Potentials and the Nernst Equation
- 3.12. Problems
- 4.1. Introduction
- 4.2. Coexistence of Phases: Gibbs Phase Rule
- 4.3. Classification of Phase Transitions
- 4.4. Classical Pure PVT Systems
- 4.4.1. Phase Diagrams
- 4.4.2. Coexistence Curves: Clausius-Clapeyron Equation
- 4.4.3. Liquid-Vapour Coexistence Region
- 4.4.4. The van der Waals Equation
- 4.4.5. Steam Engines
- The Rankine Cycle
- 4.5. Binary Mixtures
- 4.5.1. Equilibrium Conditions
- 4.6. The Helium Liquids
- 4.6.1. Liquid He4
- 4.6.2. Liquid He3
- 4.6.3. Liquid He3-He4 Mixtures
- 4.7. Superconductors
- 4.8. Ginzburg-Landau Theory
- 4.8.1. Continuous Phase Transitions
- 4.8.2. First-Order Transitions
- 4.8.3. Some Applications of Ginzburg-Landau Theory
- 4.9. Critical Exponents
- 4.9.1. Definition of Critical Exponents
- 4.9.2. The Critical Exponents for Pure PVT Systems
- 4.9.3. The Critical Exponents for the Curie Point
- 4.9.4. The Critical Exponents for Mean Field Theories
- 4.10. Problems
- 5.1. Introduction
- 5.2. Probability Density Operator
- Canonical Ensemble
- 5.2.1. Energy Fluctuations
- 5.3. Semi-Classical Ideal Gas of Indistinguishable Particles
- 5.3.1. Approximations to the Partition Function for Semi-Classical Ideal Gases
- 5.3.2. Maxwell-Boltzmann Distribution
- 5.4. Interacting Classical Fluids
- 5.4.1. Density Correlations and the Radial Distribution Function
- 5.4.2. Magnetization Density Correlations
- 5.5. Heat Capacity of a Debye Solid
- 5.6. Order-Disorder Transitions on Spin Lattices
- 5.6.1. Exact Solution for a One-Dimensional Lattice
- 5.6.2. Mean Field Theory for a d-Dimensional Lattice
- 5.6.3. Mean Field Theory of Spatial Correlation Functions
- 5.6.4. Exact Solution to Ising Lattice for d = 2
- 5.7. Scaling
- 5.7.1. Homogeneous Functions
- 5.7.2. Widom Scaling
- 5.7.3. Kadanoff Scaling
- 5.8. Microscopic Calculation of Critical Exponents
- 5.8.1. General Theory
- 5.8.2. Application to Triangular Lattice
- 5.8.3. The S4 Model
- 5.9. Problems
- 6.1. Introduction
- 6.2. The Grand Canonical Ensemble
- 6.2.1. Particle Number Fluctuations
- 6.2.2. Ideal Classical Gas
- 6.3. Adsorption Isotherms
- 6.4. Virial Expansion for Interacting Classical Fluids
- 6.4.1. Virial Expansion and Cluster Functions
- 6.4.2. The Second Virial Coefficient, B2(T)
- 6.5. Blackbody Radiation
- 6.6. Ideal Quantum Gases
- 6.7. Ideal Bose-Einstein Gas
- 6.7.1. Bose-Einstein Condensation
- 6.7.2. Experimental Observation of Bose-Einstein Condensation
- 6.8. Bogoliubov Mean Field Theory
- 6.9. Ideal Fermi-Dirac Gas
- 6.10. Magnetic Susceptibility of an Ideal Fermi Gas
- 6.10.1. Paramagnetism
- 6.10.2. Diamagnetism
- 6.11. Momentum Condensation in an Interacting Fermi Fluid
- 6.12. Problems
- 7.1. Introduction
- 7.2. Brownian Motion
- 7.2.1. Langevin Equation
- 7.2.2. Correlation Function and Spectral Density
- 7.3. The Fokker-Planck Equation
- 7.3.1. Probability Flow in Phase Space
- 7.3.2. Probability Flow for Brownian Particle
- 7.3.3. The Strong Friction Limit
- 7.4. Dynamic Equilibrium Fluctuations
- 7.4.1. Regression of Fluctuations
- 7.4.2. Wiener-Khintchine Theorem
- 7.5. Linear Response Theory and the Fluctuation-Dissipation Theorem
- 7.5.1. The Response Matrix
- 7.5.2. Causality
- 7.5.3. The Fluctuation-Dissipation Theorem
- 7.5.4. Power Absorption
- 7.6. Microscopic Linear Response Theory
- 7.6.1. Density Operator Perturbed by External Field
- 7.6.2. The Electric Conductance
- 7.6.3. Power Absorption
- 7.7. Thermal Noise in the Electron Current
- 7.8. Problems
- 8.1. Introduction
- 8.2. Navier-Stokes Hydrodynamic Equations
- 8.2.1. Balance Equations
- 8.2.2. Entropy Source and Entropy Current
- 8.2.3. Transport Coefficients
- 8.3. Linearized Hydrodynamic Equations
- 8.3.1. Linearization of the Hydrodynamic Equations
- 8.3.2. Transverse Hydrodynamic Modes
- 8.3.3. Longitudinal Hydrodynamic Modes
- 8.3.4. Dynamic Correlation Function and Spectral Density
- 8.4. Light Scattering
- 8.4.1. Scattered Electric Field
- 8.4.2. Intensity of Scattered Light
- 8.5. Friction on a Brownian particle
- 8.6. Brownian Motion with Memory
- 8.7. Hydrodynamics of Binary Mixtures
- 8.7.1. Entropy Production in Binary Mixtures
- 8.7.2. Fick's Law for Diffusion
- 8.7.3. Thermal Diffusion
- 8.8. Thermoelectricity
- 8.8.1. The Peltier Effect
- 8.8.2. The Seebeck Effect
- 8.8.3. Thomson Heat
- 8.9. Superfluid Hydrodynamics
- 8.9.1. Superfluid Hydrodynamic Equations
- 8.9.2. Sound Modes
- 8.10. Problems
- 9.1. Introduction
- 9.2. Elementary Transport Theory
- 9.2.1. Transport of Molecular Properties
- 9.2.2. The Rate of Reaction
- 9.3. The Boltzmann Equation
- 9.3.1. Derivation of the Boltzmann Equation
- 9.4. Linearized Boltzmann Equations for Mixtures
- 9.4.1. Kinetic Equations for a Two-Component Gas
- 9.4.2. Collision Operators
- 9.5. Coefficient of Self-Diffusion
- 9.5.1. Derivation of the Diffusion Equation
- 9.5.2. Eigenfrequencies of the Lorentz-Boltzmann Equation
- 9.6. Coefficients of Viscosity and Thermal Conductivity
- 9.6.1. Derivation of the Hydrodynamic Equations
- 9.6.2. Eigenfrequencies of the Boltzmann Equation
- 9.6.3. Shear Viscosity and Thermal Conductivity
- 9.7. Computation of Transport Coefficients
- 9.7.1. Sonine Polynomials
- 9.7.2. Diffusion Coefficient
- 9.7.3. Thermal Conductivity
- 9.7.4. Shear Viscosity
- 9.8. Beyond the Boltzmann Equation
- 9.9. Problems
- 10.1. Introduction
- 10.2. Near-Equilibrium Stability Criteria
- 10.3. The Chemically-Reacting Systems
- 10.3.1. The Brusselator
- A Non-linear Chemical Model
- 10.3.2. Boundary Conditions
- 10.3.3. Stability Analysis
- 10.3.4. Chemical Crystals
- 10.4. The Rayleigh-Bénard Instability
- 10.4.1. Hydrodynamic Equations and Boundary Conditions
- 10.4.2. Linear Stability Analysis
- 10.5. Problems
- A.1. Probability
- A.1.1. Definition of Probability
- A.1.2. Probability Distribution Functions
- A.1.3. Binomial Distributions
- A.1.4. Central Limit Theorem and the Law of Large Numbers
- A.2. Stochastic Processes
- A.2.1. Markov Chains
- A.2.2. The Master Equation
- A.2.3. Probability Density for Classical Phase Space
- A.2.4. Quantum Probability Density Operator
- A.3. Problems
- D.1. Symmetrized and Antisymmetrized States
- D.1.1. Free Particles
- D.1.2. Particle in a Box
- D.1.3. N-Particle Eigenstates
- D.1.4. Symmetrized Momentum Eigenstates for Bose-Einstein Particles
- D.1.5. Antisymmetrized Momentum Eigenstates for Fermi-Dirac Particles
- D.1.6. Partition Functions and Expectation Values
- D.2. The Number Representation
- D.2.1. The Number Representation for Bosons
- D.2.2. The Number Representation for Fermions
- D.2.3. Thermodynamic Averages of Quantum Operators
- E.1. Classical Dynamics of the Scattering Process
- E.2. The Scattering Cross-Section
- E.3. Quantum Dynamics of Low-Energy Scattering
- F.1. Useful Mathematics
- F.2. Solutions for Odd-Numbered Problems.