Metal-Organic Frameworks : Applications in Separations and Catalysis /
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| Format: | eBook |
| Language: | English |
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[Place of publication not identified] :
Wiley-VCH,
2018.
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| Subjects: | |
| Online Access: | Connect to the full text of this electronic book |
Table of Contents:
- Cover; Title Page; Copyright; Contents; Preface; Chapter 1 The Stability of Metalâ#x80;#x93;Organic Frameworks; 1.1 Introduction; 1.2 Chemical Stability; 1.2.1 Strengthening the Coordination Bond; 1.2.2 Protecting the Coordination Bond; 1.3 Thermal Stability; 1.4 Mechanical Stability; 1.5 Concluding Remarks; Acknowledgments; References; Chapter 2 Tuning the Properties of Metalâ#x80;#x93;Organic Frameworks by Post-synthetic Modification; 2.1 Introduction; 2.2 Post-synthetic Modification Reactions; 2.2.1 Covalent Post-synthetic Modification; 2.2.2 Inorganic Post-synthetic Modification.
- 2.2.3 Extent of the Reaction2.3 PSM for Enhanced Gas Adsorption and Separation; 2.3.1 PSM for Carbon Dioxide Capture and Separation; 2.3.2 PSM for Hydrogen Storage; 2.4 PSM for Catalysis; 2.4.1 Catalysis with MOFs Possessing Metal Active Sites; 2.4.2 Catalysis with MOFs containing Reactive Organic Functional Groups; 2.4.3 Catalysis with MOFs as Host Matrices; 2.5 PSM for Sequestration and Solution Phase Separations; 2.5.1 Metal Ion Sequestration; 2.5.2 Anion Sequestration; 2.5.3 Removal of Organic Molecules from Solution; 2.6 PSM for Biomedical Applications.
- 2.6.1 Therapeutic MOFs and Biosensors2.6.2 PSM by Change of Physical Properties; 2.7 Post-synthetic Cross-Linking of Ligands in MOF Materials; 2.7.1 Pre-synthetically Cross-Linked Ligands; 2.7.2 Post-synthetic Cross-Linking of MOF Linkers; 2.7.3 Post-synthetically Modifying the Nature of Cross-Linked MOFs; 2.8 Conclusions; References; Chapter 3 Synthesis of MOFs at the Industrial Scale; 3.1 Introduction; 3.2 MOF Patents from Academia versus the Industrial Approach; 3.3 Industrial Approach to MOF Scale-up; 3.4 Examples of Scaled-up MOFs; 3.5 Industrial Synthetic Routes toward MOFs.
- 3.5.1 Electrochemical Synthesis3.5.2 Continuous Flow; 3.5.3 Mechanochemistry and Extrusion; 3.6 Concluding Remarks; Acknowledgments; List of Abbreviations; References; Chapter 4 From Layered MOFs to Structuring at the Meso-/Macroscopic Scale; 4.1 Introduction; 4.2 Designing Bidimensional Networks; 4.3 Methodological Notes Regarding Characterization of 2D Materials; 4.3.1 Morphological and Structural Characterization; 4.3.2 Spectroscopic and Diffractometric Characterization; 4.4 Preparation and Characterization; 4.4.1 Bottom-Up Approaches; 4.4.2 Miscellaneous; 4.4.3 Top-Down Approaches.
- 4.5 Properties and Potential Applications4.5.1 Gas Separation; 4.5.2 Electronic Devices; 4.5.3 Catalysis; 4.6 Conclusions and Perspectives; Acknowledgments; References; Chapter 5 Application of Metalâ#x80;#x93;Organic Frameworks (MOFs) for CO2 Separation; 5.1 Introduction; 5.2 Factors Influencing the Applicability of MOFs for CO2 Capture; 5.2.1 Open Metal Sites; 5.2.2 Amine Grafting on MOFs; 5.2.3 Effects of Organic Ligand; 5.3 Current Trends in CO2 Separation Using MOFs; 5.3.1 Ionic Liquids/MOF Composites; 5.3.2 MOF Composites for CO2 Separation; 5.3.3 Water Stability of MOFs.