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Liquid phase aerobic oxidation catalysis
industrial applications and academic perspectives
Title Page; Copyright; Table of Contents; Preface; List of Contributors; Part I: Radical Chain Aerobic Oxidation; Chapter 1: Overview of Radical Chain Oxidation Chemistry; 1.1 Introduction; 1.2 Chain Initiation; 1.3 Chain Propagation; 1.4 Formation of Ring-Opened By-Products in the Case of Cyclohexane Oxidation; 1.5 Complications in the Case of Olefin Autoxidation; 1.6 Summary and Conclusions; References; Chapter 2: Noncatalyzed Radical Chain Oxidation: Cumene Hydroperoxide; 2.1 Introduction; 2.2 Chemistry and Catalysis; 2.3 Process Technology; 2.4 New Developments; References
Chapter 3: Cyclohexane Oxidation: History of Transition from Catalyzed to Noncatalyzed3.1 Introduction; 3.2 Chemistry and Catalysis; 3.3 Process Technology; 3.4 New Developments; Epilogue; References; Chapter 4: Chemistry and Mechanism of Oxidation of para-Xylene to Terephthalic Acid Using Co-Mn-Br Catalyst; 4.1 Introduction; 4.2 Chemistry and Catalysis; 4.3 Process Technology; 4.4 New Developments; 4.5 Conclusions; References; Part II: Cu-Catalyzed Aerobic Oxidation; Chapter 5: Cu-Catalyzed Aerobic Oxidation: Overview and New Developments; 5.1 Introduction; 5.2 Chemistry and Catalysis
5.3 Process Technology5.4 New Developments: Pharmaceutical Applications of Cu-Catalyzed Aerobic Oxidation Reactions; References; Chapter 6: Copper-Catalyzed Aerobic Alcohol Oxidation; 6.1 Introduction; 6.2 Chemistry and Catalysis; 6.3 Prospects for Scale-Up; 6.4 Conclusions; References; Chapter 7: Phenol Oxidations; 7.1 Polyphenylene Oxides by Oxidative Polymerization of Phenols; 7.2 2,3,5-Trimethylhydroquinone as a Vitamin E Intermediate via Oxidation of Methyl-Substituted Phenols; References; Part III: Pd-Catalyzed Aerobic Oxidation
Chapter 8: Pd-Catalyzed Aerobic Oxidation Reactions: Industrial Applications and New Developments8.1 Introduction; 8.2 Chemistry and Catalysis: Industrial Applications; 8.3 Chemistry and Catalysis: Applications of Potential Industrial Interest; 8.4 Chemistry and Catalysis: New Developments and Opportunities; 8.5 Conclusion; References; Chapter 9: Acetaldehyde from Ethylene and Related Wacker-Type Reactions; 9.1 Introduction; 9.2 Chemistry and Catalysis; 9.3 Process Technology (Wacker Process); 9.4 Other Developments; References; Further Reading; Chapter 10: 1,4-Butanediol from 1,3-Butadiene
10.1 Introduction10.2 Chemistry and Catalysis; 10.3 Process Technology; 10.4 New Developments; 10.5 Summary and Conclusions; References; Chapter 11: Mitsubishi Chemicals Liquid Phase Palladium-Catalyzed Oxidation Technology: Oxidation of Cyclohexene, Acrolein, and Methyl Acrylate to Useful Industrial Chemicals; 11.1 Introduction; 11.2 Chemistry and Catalysis; 11.3 Prospects for Scale-Up; 11.4 Conclusion; References; Chapter 12: Oxidative Carbonylation: Diphenyl Carbonate; 12.1 Introduction; 12.2 Chemistry and Catalysis; 12.3 Prospects for Scale-Up; 12.4 Conclusions and Outlook
edited by Shannon S. Stahl and Paul L. Alsters.
Includes bibliographical references and index.
Liquid Phase Aerobic Oxidation Catalysis : Industrial Applications and Academic Perspectives