Catalysis by Unique Metal Ion Structures in Solid Matrices : From Science to Application /

Atomically dispersed metal cations and small polyatomic cationic structures co-ordinated to the surface of porous matrices exhibit different properties from the same cationic species contained in a bulk oxide or supported on amorphous carriers. This subject is treated to an extensive review, showing...

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Bibliographic Details
Main Author: Centi, Gabriele
Corporate Author: SpringerLink (Online service)
Other Authors: Wichterlová, Blanka, Bell, Alexis T.
Format: eBook
Language:English
Published: Dordrecht : Springer Netherlands : Imprint : Springer, 2001.
Series:NATO science series. Mathematics, physics, and chemistry ; 13.
Subjects:
Online Access:Connect to the full text of this electronic book
Description
Summary:Atomically dispersed metal cations and small polyatomic cationic structures co-ordinated to the surface of porous matrices exhibit different properties from the same cationic species contained in a bulk oxide or supported on amorphous carriers. This subject is treated to an extensive review, showing how an understanding of it is essential to the development of a new generation of solid catalysts. There are also exciting opportunities to shape the catalytic properties of the transition metal cations in microporous and mesoporous matrices. <br/> The book covers both theoretical and experimental aspects, including the distribution of framework Al atoms in Si-rich zeolites, distribution and siting of charge-exchanged metal cations, electronic, adsorptive and catalytic properties of metal cations, and correlation of metal cation structure and siting with catalytic activity.
Item Description:Electronic resource.
Physical Description:1 online resource (324 pages)
ISBN:9789401007825 (electronic bk.)
9401007829 (electronic bk.)