Polyoxometalate Molecular Science /

Polyoxometalates (POMs) form a large, distinctive class of molecular inorganic compounds of unrivaled electronic versatility and structural variation, with impacts ranging from chemistry, catalysis, and materials science to biology, and medicine. This book covers the basic principles governing the s...

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Bibliographic Details
Main Author: Borrás-Almenar, Juan J.
Corporate Author: SpringerLink (Online service)
Other Authors: Coronado, Eugenio, Müller, Achim, Pope, Michael
Format: eBook
Language:English
Published: Dordrecht : Springer Netherlands : Imprint : Springer, 2003.
Series:NATO science series. Mathematics, physics, and chemistry ; 98.
Subjects:
Online Access:Connect to the full text of this electronic book
Table of Contents:
  • Preface
  • <STRONG>I: Basic Concepts and Principles.-</STRONG> Introduction to Polyoxometalate Chemistry<EM>.-</EM> General Principles of the Synthesis of Polyoxometalates in Aqueous Solution<EM>.-</EM> General Strategies for Non-Aqueous Polyoxometalate Synthesis<EM>.-</EM> Complex Oxides as Molecular Materials: Structure and Bonding in High-valent Early Transition Metal Compounds<EM>.-</EM> Physical Methods in Studying Polyoxometalates: Extended Hückel Molecular Orbital Calculations and Spectroscopic Properties<EM>.-</EM> Time-resolved Electron Spin Resonance Spectroscopy of Photoredox Reactions of Polyoxometalates: Formation of Paramagnetic Species Pair by Triplet Mechanism-<EM>.</EM><STRONG>II: Relevant Types of POM Compounds.</STRONG> Functionalized Polyoxometalates<EM>.-</EM> Sulfur-containing Keggin Anions and Cyclic Polyoxothioanions<EM>.-</EM> Magnetic Polyoxometalates<EM>.-</EM> Combinatorially Linkable Metal-oxide Based Units: Perspectives for Nano, Supramolecular, and Solid-state Chemistry<EM>
  • </EM><STRONG>III: Materials and Applications.</STRONG> Applications of Polyoxometalates in Homogeneous Catalysis<EM>.-</EM> Heterogeneous Catalysis by Heteropoly Compounds<EM>.-</EM> Photochemistry and Photocatalysis by Polyoxometalates<EM>.-</EM> Hybrid Metals Based on Polyoxometalates with Solid State Properties<EM>.-</EM> Polyoxometalates in Tailored Supramolecular Architectures: from Structure to Function<EM>.-</EM> Index
  • List of Contributors.