S Sulfur-nitrogen compounds. Part 10a, Compounds with sulfur of oxidation number II /
This volume treats the acyclic sulfur(II)-nitrogen compounds with one-coordinate and two-coordinate sulfur. Sulfur imide (S=NH) and N-organyl-sulfur imides (S=NR) are unstable compounds which can be stabilized by coordination to transition metals or trapped, for example, by Ä2 + 4Ü cycloaddition wit...
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| Other Authors: | , , |
| Format: | eBook |
| Language: | English |
| Published: |
Berlin :
Springer,
1994.
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| Edition: | 8th ed. / 8., völlig neu bearbeitete Aufl. |
| Series: | Gmelin handbook of inorganic and organometallic chemistry = Gmelin Handbuch der anorganischen Chemie ;
S,S-N, 10a. |
| Subjects: | |
| Online Access: | Connect to the full text of this electronic book |
| Summary: | This volume treats the acyclic sulfur(II)-nitrogen compounds with one-coordinate and two-coordinate sulfur. Sulfur imide (S=NH) and N-organyl-sulfur imides (S=NR) are unstable compounds which can be stabilized by coordination to transition metals or trapped, for example, by Ä2 + 4Ü cycloaddition with 1,3-butadiene. Among dithionitryl (1+) salts, only ÄS=N=SÜ+AsF6- has been studied extensively. Cycloaddition with alkenes and triple bond compounds produce 1,3,2-dithiazolium salts. Thiohydroxylamine, HSNH2, has been detected in the gas phase. Numerous examples of N,N-diorganyl-amino-halogeno-sulfanes (XSNR2, X = F, Cl, Br, I; R = organyl) and salts of the cation (XS)2N+ (X = Cl, Br) are known. N,N-Diorganyl-amino-chloro-sulfanes are important synthetic reagents. |
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| Item Description: | Electronic resource. |
| Physical Description: | 1 online resource (xxiv, 324 pages) |
| ISBN: | 9783662063514 (electronic bk.) 3662063514 (electronic bk.) |