Design of shallow p-type dopants in ZnO : preprint /
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| Other Authors: | , |
| Format: | Government Document eBook |
| Language: | English |
| Published: |
Golden, Colo. :
National Renewable Energy Laboratory,
[2008]
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| Series: | Conference paper (National Renewable Energy Laboratory (U.S.)) ;
590-42522. |
| Subjects: | |
| Online Access: | http://purl.fdlp.gov/GPO/gpo23721 http://purl.fdlp.gov/GPO/gpo25721 |
| Abstract: | Due to the large electronegativity of the oxygen, the ionization energies of acceptors in metal oxides such as ZnO is quite high, making p-type doping a great challenge for the full utilization of ZnO as optoelectronic materials. By analyzing the defect wavefunction characters, we propose several approaches to lower the acceptor ionization energy in ZnO by codoping acceptors with donor or isovalent atoms. We also proposed a universal approach to overcome the doping polarity problem for wide-band-gap semiconductors. This approach can reduce the ionization energies of dopants and the spontaneous compensation from intrinsic defects by effective doping of impurity bands, which can be achieved by introducing passive donor-acceptor complexes or isovalent impurities. The approaches described here for ZnO can be easily extended to other transparent conducting oxides used for solar cell applications. |
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| Item Description: | Title from title screen (viewed June 9, 2008). "May 2008." "Presented at the 33rd IEEE Photovoltaic Specialists Conference, San Diego, California, May 11-16, 2008." "The submitted manuscript has been offered by an employee of the Midwest Research Institute (MRI), a contractor of the US Government under Contract Number DE-AC36-99GO10337." Electronic resource. |
| Physical Description: | 1 online resource (4 pages) : illustrations |
| Bibliography: | Includes bibliographical references (page 4). |