Investigation of the emission properties of quantum dot-thermoresponsive polymer nanocomposite hydrogels with temperature /
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| Other Authors: | , |
| Format: | Thesis eBook |
| Language: | English |
| Published: |
[College Station, Tex.] :
[Texas A&M University],
[2011]
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| Subjects: | |
| Online Access: | Link to OAK Trust copy |
| Abstract: | This thesis presents a novel method for the preparation of quantum dot-thermoresponsive polymer nanocomposite hydrogels. The quantum dots (QD's) were synthesized in a microwave reactor using a high temperature organometallic synthesis procedure. The initial hydrophobic surface layer on the QD's was coated with an amphiphilic polymer to enable phase transfer from non-polar solvent to water followed by physical immobilization of the QD's in the thermoresponsive polymer hydrogel by photopolymerization. Their temperature dependent emission properties were investigated as a function of concentration of the incorporated QD's. The resultant temperature dependent changes in the position of the peak emission wavelength of the QD-polymer nanocomposite hydrogels were found to be due to the change in the physical environment causing increased interaction between the embedded amphiphilic polymer coated QD's and/or due to aggregation of QD's. This change in peak emission position was found to be reversible in the temperature range from 29 to 37 °C. |
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| Item Description: | "Major Subject: Biomedical Engineering" Title from author supplied metadata (automated record created 2011-08-09 15:09:44). Electronic resource. |
| Physical Description: | 1 online resource. |
| Bibliography: | Includes bibliographical references. |