Cumulenes in click reactions /
Cumulenes are organic molecules with two or more cumulative (consecutive) double bonds. Their reactions often proceed at room temperature, with or without a catalyst, and are stereospecific, giving the reaction products in high yields - features characteristic of "click reactions". . Cumul...
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| Format: | eBook |
| Language: | English |
| Published: |
Chichester, U.K. :
Wiley,
2009.
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| Series: | Wiley online library.
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| Subjects: | |
| Online Access: | Connect to the full text of this electronic book |
| Summary: | Cumulenes are organic molecules with two or more cumulative (consecutive) double bonds. Their reactions often proceed at room temperature, with or without a catalyst, and are stereospecific, giving the reaction products in high yields - features characteristic of "click reactions". . Cumulenes in Click Reactions presents a comprehensive list of cumulene systems and their reactions, with an emphasis on their "click-like" nature. The chapters are structured according to the number of carbon atoms in the system, including coverage of:.: introduction to the chemistry of cumulenes; one-carbon cumulenes: sulfines, sulfenes, thiocarbonyl S-imides, thiocarbonyl S-sulfides, and 1-aza-2-azoniaallene salts; two-carbon cumulenes: carbon oxides, carbon sulfides, carbon nitrides (isocyanates, isothiocyanates, and carbodiimides), phosphaallenes, and diarsaallenes; 1,2-dicarbon cumulenes: ketenes, thioketenes, ketenimines, 1-silaallenes, 1-phosphaallenes, and other metal allenes; 1,3-dicarbon cumulenes: thiocarbonyl S-ylides, 2-azaallenium salts, 1-oxa-3-azoniabutatriene salts, 1-thia-3-azoniabutatriene salts, and phosphorous ylides; 1,2,3-tricarbon cumulenes: allenes, butatrienes, higher cumulenes and heterobutatrienes; noncarbon cumulenes: azides, triazaallenium salts, sulfur oxides, sulfur nitrides, N-sulfinylamines, sulfurdiimides, and dithionitronium cation. Cumulenes in Click Reactionsis an essential guide for researchers and advanced students in academia and research working in synthetic organic, inorganic and bioorganic chemistry. |
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| Item Description: | Electronic resource. |
| Physical Description: | 1 online resource (x, 552 pages) : illustrations |
| Bibliography: | Includes bibliographical references and index. |
| ISBN: | 0470747935 (electronic bk.) 0470747951 0470779322 (hb) 6612461071 9780470747933 (electronic bk.) 9780470747957 9780470779323 (hb) 9786612461071 |
| DOI: | 10.1002/9780470747957 |