Hydride production in zircaloy-4 as a function of time and temperature /

Bibliographic Details
Main Author: Parkison, Adam Joseph
Other Authors: McDeavitt, Sean M. (Thesis advisor)
Format: Thesis eBook
Language:English
Published: [College Station, Tex.] : [Texas A&M University], [2010]
Subjects:
Online Access:Link to OAK Trust copy

MARC

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100 1 |a Parkison, Adam Joseph. 
245 1 0 |a Hydride production in zircaloy-4 as a function of time and temperature /  |c by Adam Joseph Parkison. 
264 1 |a [College Station, Tex.] :  |b [Texas A&M University],  |c [2010] 
300 |a 1 online resource. 
336 |a text  |b txt  |2 rdacontent 
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500 |a "Major Subject: Nuclear Engineering" 
500 |a Title from author supplied metadata (automated record created 2010-03-12 12:08:51). 
502 |b Master of Science  |c Texas A&M University  |d 2008  |o http://hdl.handle.net/1969.1/ETD-TAMU-2788 
504 |a Includes bibliographical references. 
516 |a Text (Thesis) 
520 3 |a The experiments performed for this thesis were designed to define the primary process variables of time, temperature, and atmosphere for an engineering system that will produce metal powder from recycled nuclear fuel cladding. The proposed system will hydride and mill Zircaloy cladding tubes to produce fine hydride powder and then dehydride the powder to produce metal; this thesis is focused on the hydride formation reaction. These experiments were performed by hydriding nuclear grade Zircaloy-4 tubes under flowing argon-5% hydrogen for various times and temperatures. The result of these experiments is a correlation which relates the rate of zirconium hydride formation to the process temperature. This correlation may now be used to design a method to efficiently produce zirconium hydride powder. It was observed that it is much more effective to hydride the Zircaloy-4 tubes at temperatures below the a-B-d eutectoid temperature of 540 C. These samples tended to readily disassemble during the hydride formation reaction and were easily ground to powder. Hydrogen pickup was faster above this temperature but the samples were generally tougher and it was difficult to pulverize them into powder. 
500 |a Electronic resource. 
650 4 |a Major nuclear engineering. 
653 |a nuclear 
653 |a cladding 
653 |a zircaloy 
653 |a hydride 
653 |a zirconium 
653 |a reprocess 
700 1 |a McDeavitt, Sean M.,  |e thesis advisor. 
856 4 0 |u http://hdl.handle.net/1969.1/ETD-TAMU-2788  |z Link to OAK Trust copy  |t 0 
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