rdf-syntax-grammar
mods:
  schema location: http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
  title info:
    title: Expanded use of bicyclic guanidinate ligands in dimetal paddlewheel compounds
  name:
    name part: Young, Mark David.
    role:
      role term: creator
  name:
    name part: Murillo, Carlos A.
    role:
      role term: thesis advisor.
  name:
    name part: Darensbourg, Marcetta Y.
    role:
      role term: thesis advisor.
  type of resource: text
  genre: bibliography
  origin info:
    place:
      place term: txu
    date issued: 2010
    issuance: monographic
  language:
    language term: eng
  physical description:
    form: electronic
    form: remote
    extent: 1 online resource.
  abstract: This dissertation concerns the use of bicyclic guanidinate ligands to prepare new dimetal paddlewheel compounds. Specifically, Ru₂⁶⁺, Re₂⁶⁺, Re₂⁷⁺, and Os₂⁷⁺ compounds will be examined to observe any changes brought about by using bicyclic guanidinate ligands with varying ring sizes. In the Ru₂⁶⁺ compounds, different ligand ring sizes cause a change in the electronic configuration and magnetic properties. Bicyclic guanidinate ligands allow the preparation of Re₂⁷⁺ compounds from Re₂⁶⁺ compounds, both of which are examined structurally and electrochemically. [Os₂(hpp)₄]⁺ is examined to improve upon earlier studies, yielding a model of the g-tensor components with respect to the compound structure. An additional project included in the dissertation involves the study of an asymmetric trinickel extended metal atom chain. The structural effects of the asymmetry are examined to help elucidate the magnetic behavior that differs significantly from symmetric trinickel extended metal atom chains.
  note: by Mark David Young.
  note: "Major Subject: Chemistry"
  note: Title from author supplied metadata (automated record created 2010-03-12 12:08:51).
  note: Electronic resource.
  note: Doctor of Philosophy Texas A&M University 2009 http://hdl.handle.net/1969.1/ETD-TAMU-2009-05-514
  note: Includes bibliographical references.
  note: Text (Dissertation)
  subject:
    topic: Major chemistry
  subject:
    topic: Metal-metal bonds
  subject:
    topic: guanidinate
  subject:
    topic: magnetism
  subject:
    topic: EPR.
  identifier: http://hdl.handle.net/1969.1/ETD-TAMU-2009-05-514
  record info:
    record content source: TXA
    record creation date: 100430
    record change date: 20151201150229.0
    record identifier: in00002557950