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| LEADER |
00000cam a2200000Ka 4500 |
| 001 |
in00002494821 |
| 005 |
20151110085932.0 |
| 006 |
m f d |
| 007 |
cr unu|||||||| |
| 008 |
090331s2008 txu sbm 000 0 eng d |
| 035 |
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|a (OCoLC)ocn317500327
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| 035 |
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|a (OCoLC)317500327
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| 035 |
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|a (TxCM)http://handle.tamu.edu/1969.1/86006
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| 040 |
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|a TXA
|c TXA
|d UtOrBLW
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| 049 |
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|a TXAM
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| 099 |
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|a 2008
|a Thesis
|a 1969.1/86006
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| 100 |
1 |
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|a Xu, Xin,
|d 1975-
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| 245 |
1 |
0 |
|a Direct conversion of carboxylate salts to carboxylic acids via reactive extraction /
|c by Xin Xu.
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| 264 |
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1 |
|a [College Station, Tex.] :
|b [Texas A&M University],
|c [2008]
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| 336 |
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|a text
|b txt
|2 rdacontent
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| 337 |
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|a computer
|b c
|2 rdamedia
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| 338 |
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|a online resource
|b cr
|2 rdacarrier
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| 500 |
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|a "Major Subject: Chemical Engineering"
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| 500 |
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|a Title from author supplied metadata (automated record created on Oct. 13, 2008.)
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| 500 |
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|a Vita.
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| 500 |
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|a Abstract.
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| 502 |
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|b M. S.
|c Texas A&M University
|d 2008.
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| 504 |
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|a Includes bibliographical references.
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| 516 |
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|a Text (M. S.).
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| 520 |
3 |
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|a The MixAlco process, a proprietary technology owned by Texas A&M University, converts biomass (e.g., municipal solid waste, sewage sludge, paper, agricultural residues, and energy crops) into usable chemicals (e.g., acetic acid) and fuels (e.g., ethanol). Historically, calcium carbonate has been used as the buffer. Recently, it was found that using ammonium bicarbonate as the buffering agent enhances the fermentation conversion. In this case, fermentation broth contains ammonium salts (e.g., ammonium acetate, propionate, butyrate, pentanoate). Therefore, the downstream processing steps (including extraction, purification, esterification, and product separation) must be compatible with the ammonium carboxylate salts formed in the fermentation. This research focuses on converting fermentation broth carboxylate salts into their corresponding acids via "acid springing." Reactive extraction and thermal conversion (distillation) are crucial parts of the acid springing process. Because the components of the fermentation broth are over 80% ammonium acetate and 20% other ammonium carboxylate salts (ammonium propionate, butyrate, pentanoate, etc.), all the initial experiments in this study were performed using reagentgrade ammonium acetate to simplify the reaction. Later, actual fermentation broth was employed. The primary objective of this study was to provide the optimal operating conditions to make the downstream processing steps of the MixAlco process compatible with ammonium carboxylate salts formed in the fermentation. The optimal initial concentration for reactive extraction should be 150-200 g/L and the volume ratio of aqueous phase and extractant should be 1:1. The distribution coefficient reaches the maximum value when the concentration of TOA is 20% (vol %) in n-octanol. The batch distillation study shows that there are two reaction stages: (1) water leaves the system at 100-106 °C and (2) the acid-amine complex decomposes at 160-180 °C.
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| 538 |
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|a Mode of access: World Wide Web.
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| 538 |
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|a System requirements: World Wide Web access and Adobe Acrobat Reader.
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| 500 |
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|a Electronic resource.
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| 650 |
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4 |
|a Major chemical engineering.
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| 653 |
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|a REACTIVE EXTRACTION
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| 653 |
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|a CARBOXYLIC ACIDS
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| 700 |
1 |
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|a Holtzapple, Mark T.,
|e thesis advisor.
|
| 856 |
4 |
0 |
|u http://hdl.handle.net/1969.1/86006
|z Link to OAK Trust copy
|t 0
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| 994 |
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|a C0
|b TXA
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| 948 |
|
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|a cataloged
|b h
|c 2009/3/31
|d c
|e jlanham
|f 10:44:41 am
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| 999 |
|
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|a MARS
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| 999 |
f |
f |
|s f1b455ec-c26c-3290-b960-5e00a1d06418
|i ee5d3bdc-9b29-32e5-96fc-3bdd9a7009d9
|t 0
|
| 952 |
f |
f |
|a Texas A&M University
|b College Station
|c Electronic Resources
|d Available Online
|t 0
|e 2008 Thesis 1969.1/86006
|h Other scheme
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| 998 |
f |
f |
|a 2008 Thesis 1969.1/86006
|t 0
|l Available Online
|