rdf-syntax-grammar
mods:
  schema location: http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
  title info:
    title: Alkene polymerization reactions with transition metal catalysts
  name:
    name part: Kissin, Y. V.
    role:
      role term: creator
  name:
    name part: ScienceDirect (Online service)
  type of resource: text
  genre: bibliography
  genre: Electronic books.
  origin info:
    place:
      place term: ne
    date issued: 2008
    issuance: monographic
  language:
    language term: eng
  physical description:
    form: electronic
    form: remote
    extent: xiv, 592 pages : illustrations ; 25 cm.
  abstract: During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts. 4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes s…
  table of contents: Chapter 1. The beginners course. General description of transition metal catalysts and catalytic polymerization reactions -- Chapter 2. Single-center and multi-center polymerization catalysis -- Chapter 3. Chemistry and stereochemistry of polymerization and copolymerization reactions with transition metal catalysts -- Chapter 4. Synthesis, chemical composition, and structure of transition metal catalysts for alkene polymerization -- Chapter 5. Kinetics of alkene polymerization reactions with transition metal catalysts -- Chapter 6. Active centers in transition metal catalysts and mechanisms of polymerization reactions.
  note: Yury V. Kissin.
  note: Electronic resource.
  note: Electronic reproduction. Amsterdam : Elsevier Science & Technology, 2008. Mode of access: World Wide Web. System requirements: Web browser. Title from title screen (viewed on May 14, 2008). Access may be restricted to users at subscribing institutions.
  note: Includes bibliographical references and index.
  subject:
    topic: Polymerization
  subject:
    topic: Transition metal catalysts
  classification: QD281.P6 K54 2008eb
  classification: 541.39
  related item:
    identifier: (OCoLC)176824444
  related item:
    title info:
      title: Studies in surface science and catalysis ; 173
  identifier: 9780444532152
  identifier: 0444532153
  identifier: 117000:117100 Elsevier Science & Technology
  identifier: http://proxy.library.tamu.edu/login
  record info:
    record content source: OPELS
    record creation date: 080516
    record change date: 20260609193441.0
    record identifier: in00002433870