The vanadyl complex of N,N'-bis(2-mercaptoethyl)-1, 5-diazacyclooctane /
(bme-daco)VO, exhibits square-pyramidal geometry about the
| Main Author: | |
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| Format: | Thesis eBook |
| Language: | English |
| Published: |
[Place of publication not identified] :
[publisher not identified] ;
1997.
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| Subjects: | |
| Online Access: | Link to OAKTrust copy |
| Summary: | (bme-daco)VO, exhibits square-pyramidal geometry about the appears that the electron withdrawing capacity of the vanadyl applications in the crude oil industry as well as in the basal plane and the 0-atom at the apex. The vanadium atom biological realm. The N2 S2 tetradentate ligand N,N'-bis(2- characterization of (bme-daco)VO are discussed and the complex is compared to other square-pyramidal systems of bme- daco, including [Ga-C,12,. In light of the reactivity of the daco)VO was examined and compared to the former complex. It electrophiles; however, some reactivity was seen with hydrogen peroxide and sulfur dioxide. lies 0.66 A above the best N2S2 plane. The synthesis and mercaptoethyl)-l@5-diazacyclooctane, H2-bme-daco, has been nickel(II) analogue of (bme-daco)VO, the reactivity of (bme- oxygen deactivates the thiolate sulfurs towards shown to complex the vanadyl moiety. The resulting complex, The chemistry of the divalent vanadyl cation, (VO)2 + , finds vanadium atom with the donor atoms of the ligand forming the |
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| Item Description: | "Major subject: Chemistry". In title, numerals are used. Vita. |
| Physical Description: | x, 52 leaves : illustrations ; 28 cm. Also available online. Issued also on microfiche from Lange Micrographics. |
| Bibliography: | Includes bibliographical references. |