Oxygen addition to sulfur of metal thiolates /
(BME-DACO)2Ni3 2+, resulting from electron-transfer and
| Main Author: | |
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| Format: | Thesis eBook |
| Language: | English |
| Published: |
[Place of publication not identified] :
[publisher not identified] ;
1996.
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| Subjects: | |
| Online Access: | Link to OAKTrust copy |
| Summary: | (BME-DACO)2Ni3 2+, resulting from electron-transfer and and also from their essential role in heterogeneous bis(mercaptoethyl)-1,5-diazacyclooctane-nickel(II), (BME- bismercaptoethyl-1,5-diazacyclooctane-nickel(II))-nickelate, catalysis in inorganic chemistry. The oxidation reactions complexes have been isolated, separated, and characterized. coordinated sulfur ligands derives from their potential DACO)2Ni3 +2, to produce a trimetallic, (N,N'- DACO)Ni, and N,N'-bissulfinylethyldiazacyclooctane dioxiranes, and peracids have been reviewed. The compounds formation of thiadioxirane intermediates is proposed for the ligand oxidation, as well as two oxygenates, N,N'- mercaptoethylsulfinylethyldiazacyclooctanenickel(II), (MESE- Molecular oxygen or hydrogen peroxide reacted with (N,N'- nickel(II), (BSE-DACO)Ni. A mechanism involving the of metal thiolates by hydrogen peroxide, molecular oxygen, reaction with molecular oxygen in aprotic solvent. relevance to active sites in metalloenzymes in biochemistry resulting from oxidation and oxygenation of nickel thiolate The current interest in metal complexes possessing |
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| Item Description: | "Major subject: Chemistry". Vita. |
| Physical Description: | ix, 93 leaves : illustrations ; 28 cm. Also available online. Issued also on microfiche from Lange Micrographics. |
| Bibliography: | Includes bibliographical references: pages 65-70. |