Identification and characterization of the CO Oxidation/CO2 reduction site of Ni-containing carbon monoxide dehydrogenases /

The active site for the CO Oxidation/CO2 reduction activity of carbon monoxide dehydrogenase, called the C-cluster, consists of a Fe4S4 cluster bridged to a Ni ion. One of the irons, called FCII, is either 5 or 6 coordinate and is thought to be bridged to the Ni. The cluster is coordinated by at l...

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