A study of microalloyed pure aluminum for superconductor stabilizer applications /

The effects of microalloying on the strength, resistivity,

Bibliographic Details
Main Author: McDonald, Lacy Clark, 1964-
Format: Thesis Book
Language:English
Published: [Place of publication not identified] : [publisher not identified] ; 1994.
Subjects:
Online Access:http://proxy.library.tamu.edu/login?url=http://proquest.umi.com/pqdweb?did=741965581&sid=1&Fmt=2&clientId=2945&RQT=309&VName=PQD
Description
Summary:The effects of microalloying on the strength, resistivity,
and resistivity degradation characteristics of high purity
aluminum at 4.2 K have been examined. Testing methods
primarily consisted of monitoring electrical and mechanical
properties during simulated conductor operating conditions of
0︢.001 strain at 4.2 K. Variables concerning solutes are
element type (Au, B, Ca, Ce, Ga, Sn, or Y), concentration (O
to 90 wppm), and the initial material condition, which is
dependent on processing. The results show that microalloying
at levels of about 10 appm are beneficial for strengthening
and for inhibiting resistivity degradation; elements which
appear to be particularly effective are Ce and Y. However,
although evidence for Cottrell atmospheres was found with
solute concentrations below 10 appm, improvements attributed
to microalloying are actually an indirect result of grain
refinement that occurs with microalloying. A fine grain
structure results in a higher work hardening rate and a lower
overall degradation; limited evidence suggests that texture
may be significant as well. TEM observations show that
cyclic deformation within a strain range of 0︢.001 at 4.2 K
does not produce a well defined dislocation subcell structure
in high purity aluminum; the dislocation arrangement is best
described as a high density of heterogeneously distributed
dislocations. Results from materials in an annealed
condition indicate that resistivity coefficients for Au, B,
Ca, Ce, Ga, Sn, and Y, at concentrations below 100 wppm, are
0.016, 0.004, 0.039, 0.001, 0.009, 0.005, and 0.015 n[
]cm/wppm, respectively. Contributions to the resistivity by
the RRR of the base metal is reduced from -10,000 to not less
than 2,500. Finally, observations of microsegregated
particles that form during solidification of the microalloys
indicate that the solubilities of B and Ca in aluminum at
room temperature are close to zero appm; solubilities of
other elements appear to be higher than those levels tested.
Item Description:Vita.
"Major Subject: Mechanical Engineering".
Physical Description:xix, 271 leaves : illustrations ; 28 cm.
Issued also on microfiche from University Microfilms Inc.
Bibliography:Includes bibliographical references.