rdf-syntax-grammar
mods:
  schema location: http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
  title info:
    title: Electrodeposition of Cu and Ag on Pd(111)
  name:
    name part: Cali, George John.
    role:
      role term: creator
  name:
    name part: Soriaga, M. P.
    role:
      role term: degree supervisor.
  name:
    name part: Fry, E. S.
    role:
      role term: degree committee member.
  name:
    name part: Goodman, D. W.
    role:
      role term: degree committee member.
  name:
    name part: Vigh, Gy.
    role:
      role term: degree committee member.
  name:
    name part: Texas A & M University
    role:
      role term: degree granting institution.
  type of resource: text
  genre: bibliography
  genre: Academic theses
  origin info:
    place:
      place term: xx
    date issued: 1991
    issuance: monographic
  language:
    language term: eng
  physical description:
    form: print
    extent: x, 146 leaves : illustrations ; 29 cm
  abstract: Atomic layers of Cu and Ag on single crystal Pd(111) electrode surfaces were prepared in H2SO4 and HCIO4 solutions under carefully controlled conditions and then characterized by electrochemical methods in parallel with two surface-sensitive electron spectroscopies, low energy electron diffraction (LEED) and Auger electron spectroscopy (AES). A particular effort was made in order to obtain quantitative measurements of Cu and Ag deposits for which there was evidence of good surface structure. These determinations were done in situ using three electrochemical techniques. Monolayer deposits of Cu when exposed to dilute iodide solutions produced a Pd(111)-([square root]3 x 5)-Cu,I LEED pattern. The iodine overlayer provided for the elegant control of the interfacial properties of the Cu-Pd surface. In vacuum, the iodine protected the Cu deposit from attack by oxygen, and in solution, it facilitated the electrochemical removal of the underlying Cu from the Pd(111) surface. The preparation of a Pd(111)-([square root]3 x [square root]3)R30°-I surface prevented the formation of surface oxides and thus allowed the selective deposition and removal of Ag.
  note: Typescript (photocopy).
  note: Vita.
  note: "Major subject: Chemistry."
  note: Ph. D. Texas A & M University 1991
  note: Includes bibliographical references.
  subject:
    topic: Copper plating
  subject:
    topic: Silver-plating
  subject:
    topic: Palladium alloys
  subject:
    topic: Major chemistry
  identifier: http://proxy.library.tamu.edu/login
  related item:
    location:
      url: http://proxy.library.tamu.edu/login
  record info:
    record content source: TXA
    record creation date: 920923
    record change date: 20200904152543.0
    record identifier: in00001074899
    language of cataloging:
      language term: eng