rdf-syntax-grammar
mods:
  schema location: http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
  title info:
    title: Chlorine and deuteron relaxation time measurements in liquid HCl and DCl
  name:
    name part: Boehme, Hollis Clyde.
    role:
      role term: creator
  name:
    name part: Basye, Robert E.
    role:
      role term: degree committee member.
  name:
    name part: Duller, Nelson M.
    role:
      role term: degree committee member.
  name:
    name part: Eisner, Melvin
    role:
      role term: degree supervisor.
  name:
    name part: Ham, Joe S.
    role:
      role term: degree committee member.
  name:
    name part: Hedges, R. M.
    role:
      role term: degree committee member.
  name:
    name part: Texas A & M University
    role:
      role term: degree granting institution.
  type of resource: text
  genre: theses
  genre: Academic theses
  origin info:
    place:
      place term: txu
    date issued: 1967
    issuance: monographic
  language:
    language term: eng
  physical description:
    form: print
    extent: 52 leaves illustrations
  abstract: Measurements of chlorine T₂ in liquid HCl and DCl have been made over the temperature range of -40°C to 60°C. Estimates of the reorientational correlation time made possible by the chlorine measurements were used to evaluate the proton intra-molecular dipole contribution which was subtracted from the total intra-molecular contribution to obtain the proton spin-rotational contribution. The magnitude of the spin-rotational contribution thus obtained compares with that estimated by Krynicki and Powles.⁸ Deuteron T₁ times in liquid DCl were measured over the temperature range of -75°C to 25°C and found to differ considerably both in magnitude and temperature dependence from deuteron T₂ times. Estimates of the quadrupole contribution to the deuteron (1/T₁) and, thus, a value of 2.0 x 10¹⁷ volts/cm² for the electric field gradient at the deuteron site in DCl were made by use of the reorientational correlation time from chlorine measurements. The difference between experimental deuteron (1/T₁) and the deuteron quadrupole contribution to (1/T₁) was considered to be due to a deuteron-chlorine scalar interaction. The scalar contribution to the deuteron (1/T₁) and the experimental deuteron (1/T₂) were used to estimate the scalar coupling constant and deuteron exchange time in DCl.
  note: Ph. D. in Physics Texas A & M University
  subject:
    topic: Major physics
  identifier: http://proxy.library.tamu.edu/login
  identifier: https://hdl.handle.net/1969.1/DISSERTATIONS-169674
  related item:
    location:
      url: http://proxy.library.tamu.edu/login
  related item:
    location:
      url: https://hdl.handle.net/1969.1/DISSERTATIONS-169674
  record info:
    record content source: TXA
    record creation date: 791112
    record change date: 20220103135214.0
    record identifier: in00000162394
    language of cataloging:
      language term: eng