The organometallic chemistry of the group VA elements : compounds of arsenic and phosphorus containing arsinic acid, arsonic acid, arsenyl, phophinous acid or phosphinic acid groups.

Bibliographic Details
Main Author:	Kallenbach, Lyle Ray
Other Authors:	Dieckert, Julius W. (degree committee member.), Hancock, C. Kinney (degree committee member.), Kunze, George W. (degree committee member.)
Format:	Thesis Book
Language:	English
Published:	[College Station, Tex.], 1969.
Subjects:	Major chemistry. Academic theses.
Online Access:	Link to ProQuest copy Link to OAKTrust copy

Description
Abstract:	(Diethylamino)dichloroarsine and bis(diethylamino)chloroarsine have been investigated as intermediates in syntheses which lead to a variety of arsinic and arsonic acids containing branched alkyl chains and poly(polymethylenearsinic acids). (Diethylamino)dichlorophosphine was also studied as an intermediate for the synthesis of di(alkyl)phosphinous acid, di(alkyl)phosphinic acid and poly(polymethylenephosphinic acids). The following compounds were isolated and characterized: (1) (diethylamino)dichloroarsine, (2) bis(diethylamino)chloroarsine, (3) (diethylamino)dichlorophosphine, (4) bis(diethylamino)chlorophosphine, (5) di(2-ethylhexyl)arsinic acid, (6) di(1-methylheptyl)arsinic acid, (7) 2-ethylhexylarsonic acid, (8) di(1-octynyl)arsinic acid, (9) 1-octynylarsonic acid, (10) poly(hexamethylenearsinic acid), (11) poly(octamethylenearsinic acid), (12) poly(decamethylenearsinic acid), (13) di-n-octylphosphinous acid, (14) di-n-octylphosphinic acid, and (15) poly(octamethylenephosphinic acid). These compounds were characterized by means of infrared and nmr spectroscopy, viscosity measurements, differential thermal and thermal gravimetric analysis.
Physical Description:	97 leaves