Synthesis of some 1-aminophosphonic acids containing sulfur and heterocyclic rings.

Bibliographic Details
Main Author:	Holtkamp, Freddy Henry
Other Authors:	Hedges, R. M. (degree committee member.), Pearson, Karl H. (degree committee member.), Taber, Willard A. (degree committee member.)
Format:	Thesis Book
Language:	English
Published:	[College Station, Tex.], 1969.
Subjects:	Major chemistry. Academic theses.
Online Access:	Link to ProQuest copy Link to OAKTrust copy

Description
Abstract:	Three 1-aminoalkylphosphonic acids were synthesized, utilizing the modified Curtius reaction. Two of the amino phosphonic acids synthesized are analogs of naturally occurring 1-aminoalkylcarboxylic acids. The 1-aminoalkylphosphonic acids synthesized were 3-methylthio-1-aminopropyIphosphonic acid (methionine analog), 3-ethylthio-1-aminopropylphosphonic acid (ethionine analog) and 2-(3-indolyl)-1-aminoethyl-phosphonic acid (tryptophane analog). Two triethyl 2-phosphonoalkanoates, triethyl 4-methylthio-2-phosphonobutyrate and triethyl 4-ethylthio-2-phosphonobutyrate, were synthesized and characterized. ...
Physical Description:	64 leaves